(b)
$2Ag + 2HNO_{3} \longrightarrow 2AgNO_{3} + H_{2}$
$2AgNO_{3} + 2NaCl \longrightarrow 2AgCl + NaNO_{3}$
$AgCl \equiv AgNO_{3} \equiv Ag$
143.5g 170 g 108g
$\because 143.5\ g\ \ \ \ AgCl$ is obtained from $Ag = 108g$
$\therefore 2.87\ g\ AgCl$ is obtained from $Ag = \frac{108 \times 2.87}{143.5}$
$= 2.16g$