(c)
$CaCO_{3} + 2HCl\overset{\mathrm{\Delta}}{\rightarrow}CaCl_{2} + H_{2}O + CO_{2}$
100 g 2 $\times$ 36.5g 44 g
1 L of 1 N HCl means=36.5 g HCl
Here, HCl is limiting reagent. Therefore, it reacts with 50 g
$CaCO_{3}$ and produces 22 g $CO_{2}$.