(d)
The energy of second Bohr orbit of hydrogen atom $\left( E_{2} \right)\ is - 328\ kJ\ mol^{- 1}$ because
$\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ E_{2} = - \frac{1312}{2^{2}}kJ\ mol^{- 1}$
$\therefore\ \ \ \ \ \ \ \ \ \ \ \ \ E_{n} = - \frac{1312}{n^{2}}kJ\ mol^{- 1}$
If $n = 4$
$\therefore\ \ \ \ \ \ \ \ \ \ \ \ \ E_{4} = - \frac{1312}{4^{2}}kJ\ mol^{- 1}$
$\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ = - 82\ kJ\ mol^{- 1}$