(d)
Subshell having lower value of $(n + l)$ will be of lower energy, where $n$ is the principle and $l$ is the azimuthal quantum number. Thus,
Correct energy value order is
$ns,(n - 1)d,\ np,(n - 1)f$.
Reviewed by Dr. Abubacker
Physics Educator & NEET/JEE Specialist
Ph.D. in Physics with 19+ years of teaching experience.