Q. The wave number of the spectral line in the emission spectrum of hydrogen will be equal to $\frac{8}{9}$ times the Rydberg’s constant if the electron jumps from

A) $n = 3\ to\ n = 1$
B) $n = 10\ to\ n = 1$
C) $n = 9\ to\ n = 1$
D) $n = 2\ to\ n = 1$
Explanation

(a)
Wave number of spectral line in emission spectrum of hydrogen,
$\overline{v} = R_{H}\left( \frac{1}{n_{1}^{2}} - \frac{1}{n_{2}^{2}} \right)\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ldots(i)$
Given, $\overline{v} = \frac{8}{9}R_{H}$
On putting the value of $\overline{v}$ in Eq. (i), we get
$\frac{8}{9} = R_{H}\left( \frac{1}{n_{1}^{2}} - \frac{1}{n_{2}^{2}} \right)$
$\frac{8}{9} = \frac{1}{(1)^{2}} - \frac{1}{n_{2}^{2}}$
$\frac{8}{9} - 1 = - \frac{1}{n_{2}^{2}}$
$\frac{1}{3} = \frac{1}{n_{2}}\$
$\therefore\ \ \ \ \ n_{2} = 3$
Hence, electron jumps from $n_{2} = 3\ to\ n_{1} = 1$

Dr. Abubacker
Reviewed by Dr. Abubacker

Physics Educator & NEET/JEE Specialist

Ph.D. in Physics with 19+ years of teaching experience.