Q. The correct order of electron gain enthalpy with negative sign of F, Cl, Br and I, having atomic number 9, 17, 35 and 53 respectively, is

A) Cl > F > Br > I
B) F > Cl > Br > I
C) I > Br > Cl > F
D) I > Br > F > Cl
Explanation

(a)
As we go down the group in Periodic Table, atomic size increases, force of attraction for the added electron decreases, hence electron gain enthalpy decreases.
$X(g) + e^{-} \rightarrow X^{-}(g)$
Actual order, $Cl > F > Br > I$
The fact that fluorine has a less electron gain enthalpy than chlorine seems to be due to the relatively greater effectiveness of 2$p$-electron in the small F-atom to repel the additional electron entering the atom than do 3$p$-electrons in the larger Cl-atom.

Dr. Abubacker
Reviewed by Dr. Abubacker

Physics Educator & NEET/JEE Specialist

Ph.D. in Physics with 19+ years of teaching experience.