Q. The pair of elements having approximately equal ionisation potential is

A) Al, Ga
B) Al, Si
C) Al, Mg
D) Al, B
Explanation

(a)
Ionisation energy increases with decrease in atomic size and decrease in shielding effect. Ten $d$-electrons in Ga shield the nuclear charge less effectively than the s and p electrons. Hence, the outer electron is held fairly strongly by the nucleus. Consequently, ionisation energy slightly increases inspite of the increase in atomic size from Al to Ga. Hence, Al (IE=577) and Ga(IE=578) have approximately equal ionisation potential (or ionisation energy).

Dr. Abubacker
Reviewed by Dr. Abubacker

Physics Educator & NEET/JEE Specialist

Ph.D. in Physics with 19+ years of teaching experience.