(a)
Ionisation energy defined as the energy required to remove an electron from the outermost orbit of an isolated gaseous atom in its ground state.
Na(11)$= 1s^{2},2s^{2},2p^{6},3s^{1}$
$Na \rightarrow Na^{+} + e^{-}(First\ IE)$
$Na^{+} \rightarrow Na^{2 +} + e^{-}(Second\ IE)$
First IE is lower and second IE is very higher, because removal of an electron from $Na^{+}$is very difficult.