(d)
Higher the lattice energy lower the solubility. Out of the four combinations possible, the lattice energy of MgS (bi-bivalent ionic solid) is higher than those of $Na_{2}S,\ MgCl_{2}$ (uni-bivalent or biuni-valent ionic solids ) and NaCl (uni-univalent ionic solids) and hence, MgS is the least soluble.