Q. If $Na^{+}$ ion is larger than $Mg^{2 +}$ ion and $S^{2 -}$is larger than$Cl^{-}$ ion, which of the following will be stable soluble in water?

A) Sodium chloride
B) Sodium sulphide
C) Magnesium chloride
D) Magnesium sulphide
Explanation

(d)
Higher the lattice energy lower the solubility. Out of the four combinations possible, the lattice energy of MgS (bi-bivalent ionic solid) is higher than those of $Na_{2}S,\ MgCl_{2}$ (uni-bivalent or biuni-valent ionic solids ) and NaCl (uni-univalent ionic solids) and hence, MgS is the least soluble.

Dr. Abubacker
Reviewed by Dr. Abubacker

Physics Educator & NEET/JEE Specialist

Ph.D. in Physics with 19+ years of teaching experience.