Q. Structure of ${XeF}_{5}^{+}$ ion is

A) Trigonal bipyramidal
B) Square pyramidal
C) Octahedral
D) Pentagonal
Explanation

(b)
In ${XeF}_{5}^{+},$ Xe atom has only seven electrons , $i.e$., $5s^{2}\ 5p^{5}$. Here two 5p electrons are promoted to 5d-sublevel. Then 5s, three 5p and two 5d orbitals hybridize to give six $sp^{3}d^{2}$ hybrid orbitals in an octahedral geometry. Out of these five orbitals are singly occupied which form sigma bonds with five F atoms. The sixth hybrid orbital is occupied by a lone pair in $trans$ position giving a square pyramid structure.

Dr. Abubacker
Reviewed by Dr. Abubacker

Physics Educator & NEET/JEE Specialist

Ph.D. in Physics with 19+ years of teaching experience.