Q. Peroxide ion (i) has five completely filled antibonding molecular orbitals (ii) is diamagnetic (iii) has bond order one (iv) is isoelectronic with neon Which one of these is correct?

A) (ii) and (iii)
B) (i),(ii) and (iv)
C) (i),(ii) and (iii)
D) (i) and (iv)
Explanation

(a)
Peroxide ion in $O_{2}^{2 -}$
$O_{2}^{2 -}(18) =$ $\sigma 1s^{2},\ \ _{\sigma}^{*}1s^{2},\ \ _{\sigma}2s^{2},\ \ _{\sigma}^{*}2s^{2},\ \sigma 2p_{z}^{2}$
$\pi 2p_{x}^{2} = \pi 2p_{y}^{2},\ _{\pi}^{*}2p_{x}^{2} = \ _{\pi}^{*}2p_{y}^{2}$
Bond order = $\frac{N_{b} - N_{a}}{2} = \frac{10 - 8}{2}$=1
It contains four completely filled antibonding molecular orbitals. Since, all the electrons are paired, $O_{2}^{2 -}$ is diamagnetic.
Peroxide ion is isoelectronic with argon, not with neon.

Dr. Abubacker
Reviewed by Dr. Abubacker

Physics Educator & NEET/JEE Specialist

Ph.D. in Physics with 19+ years of teaching experience.