(d)
According to Gay Lussac’s law
$\frac{p_{1}}{T_{1}} = \frac{p_{2}}{T_{2}}$
If $\frac{3^{th}}{8}$ of the air is expelled out then remaining air $= \frac{5}{8}$
$T_{2} = \frac{(273 + 27) \times 8}{5}$
$= \frac{2400}{5} = 480\ K$
$= 480 - 273 = 207℃$