Q.
In $A^{+}B^{-}$ ionic compound, radii of $A^{+}$ and $B^{-}$ ions are 180 pm and 187 pm respectively. The crystal structure of this compound will be
A) $NaCl\$type
B) $CsCl$ type
C) $ZnS$ type
D) Similar to diamond
Explanation
(b)
$\frac{r_{+}}{r_{-}} = \frac{180}{187} = 0.962,$ which lies in the range of $0.732 - 1.000$, hence, coordination number 8, $ie$, the structure is $CsCl$ type
Reviewed by Dr. Abubacker
Physics Educator & NEET/JEE Specialist
Ph.D. in Physics with 19+ years of teaching experience.