(a)
White ring of ${NH}_{4}Cl$ will appear nearer to the HCl end. The reason is that HCl (mol. wt. = 36.5) is heavier than ${NH}_{3}$ (mol. wt. Hence, according to Graham’s law of diffusion, the rate of diffusion of ${NH}_{3}$ will be higher than that of HCl.)
$\frac{r_{1}}{r_{2}} = \sqrt{\frac{M_{2}}{M_{1}}}$