(d)
The reaction in which number of moles of reactants= number of moles of products are not effected by change in pressure or volume.
$H_{2}(g) + I_{2}(g) \rightleftharpoons 2HI(g)$
$\therefore$ Number of moles of reactant = number of moles of products
2=2
$\therefore$ This reaction is not effected by change in pressure or volume.