(d)
Number of milliequivalents of
$NaOH = 10 \times 0.1 = 1$
Number of milliequivalents of
$H_{2}SO_{4} = 10 \times 0.05 = 0.5$
Milliequivalent of $H_{2}SO_{4}\ will\ neutralise\ NaOH$ so, that (1-0.5)=0.5 millieq. Of $NaOH$ is left unneutralised.
Hence, pH of the resulting solution will be greater than seven (pH>7).