(c) For buffer solution, $pH = pK_{a} + \log\frac{\lbrack salt\rbrack}{\lbrack base\rbrack}$ If concentration of salt = concentration of acid $i.e$., $\lbrack salt\rbrack = \lbrack acid\rbrack$ Hence, $pH = pK_{a}$
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Ph.D. in Physics with 19+ years of teaching experience.