Q.
The exothermic formation of $ClF_{3}$ is represented by the equation
$Cl_{2}(g) + 3F_{2}(g) \rightleftharpoons 2ClF_{3}(g);\ \ \ \ \$
$\mathrm{\Delta}H = - 329\ kJ$
Which of the following will increase the quantity of $ClF_{3}$ in an equilibrium mixture of $Cl_{2},\ F_{2}\ and\ ClF_{3}$?
A) Adding $F_{2}$
B) Increasing the volume of the container
C) Removing $Cl_{2}$
D) Increasing the temperature
Explanation
(a)
Reaction is exothermic. By Le-Chatelier’s principle, a reaction is spontaneous in forward side (in the direction of formation of more $ClF_{3})\ if\ F_{2}$ is added, temperature is lowered and $ClF_{3}$ is removed.
Reviewed by Dr. Abubacker
Physics Educator & NEET/JEE Specialist
Ph.D. in Physics with 19+ years of teaching experience.