(d)
$Cu^{2 +},\ Bi^{3 +}\ and\ Cd^{2 +}$ all belong to II group of qualitative analysis while $Zn^{2 +}$ belongs to IV group. The solubility product of sulphides of IV group radicals is higher as compared to that of the II group radicals.
Hence, $ZnS$ has the highest value of solubility product.