(a)
$X\ \ \ + \ \ \ \ \ Y \rightleftharpoons \ \ \ Z$
Initial conc., 5 3 0
At equilibrium $(5 - 2)(3 - 2)\ \ \ 2$
Equilibrium constant $\left( K_{c} \right) = \frac{\lbrack Z\rbrack}{\lbrack X\rbrack\lbrack Y\rbrack}$
$= \frac{2}{3 \times 1} = \frac{2}{3}$