(a)
${\ \ \ \ \ N}_{2}\ + \ \ \ \ \ \ \ \ \ \ 3H_{2} \rightleftharpoons 2{NH}_{3}$
56 g 8 g 0 g
$( = 2\ mol)( = 4\ mol)\ (0\ mol)$ initially
$(2 - 1)(4 - 3)\ \ \ \ 34\ g$ at equilibrium
$= 1\ \ \ \ \ \ \ \ \ \ \ \ = 1\ \ \ \ \ \ ( = 2\ mol)$
According to Eq.(1) 2 moles of ammonia are present a produce 2 moles of $NH_{3},$ we need 1 mole of $N_{2}$ and 3 of $H_{2}$, hence $2 - 1 = 1$ mole of $N_{2}$ and $4 - 3\text{=}1$ mole are present at equilibrium in vessel