(d)
$PCl_{5}\ \ \ \ \rightleftharpoons \ PCl_{3}\ \ \ \ \ \ \ + \ \ \ \ Cl_{2}$
3 mol 3 mol 2 mol initially
(3-$x$) mol (3 $x$)mol (2 $x$)mol at equilibrium
$\because$ $3 - x\ \ \ \ \ \ 1.5$
$x\ \ \ \ \ \ \ 1.5$
Number of moles of $PCl_{3}\ \ \ 3\ \ \ \ x$
3 1.5 4.5