(a)
$2SO_{2}\ \ \ \ + \ \ \ O_{2}\ \ \ \ \ \rightleftharpoons \ \ \ 2SO_{3}$
Initially 4 4 0
At equili. 4(1-0.25) 4(1-0.25) $0.25 \times 2$
Total number of moles at equilibrium
$4(1 - 0.25)\ \ \ \ \ \ \ \ \ \ 4(1 - 0.25)\ \ \ \ 0.5$
$4 - 1\ \ \ \ \ \ 4 - 1\ \ \ \ \ 0.5\ \ \ \ 6.5$