Q. Equilibrium constant K, for the reaction, $2HI(g) \rightleftharpoons H_{2}(g) + I_{2}(g)$ at room temperature is 2.85 and that at 698 K is $1.4 \times 10^{- 2}$. This implies that the forward reaction is

A) Exothermic
B) Endothermic
C) Exergonic
D) Unpredictable
Explanation

(a)
$2HI(g) \rightleftharpoons H_{2}(g) + I_{2}(g)$
$K = \frac{\left\lbrack H_{2} \right\rbrack\lbrack I_{2}\rbrack}{\lbrack HI\rbrack^{2}}$
When temperature increases, $K_{c}$ decreases.
$\therefore$ Concentration of product decreases.
It means forward reaction is not favoured at higher temperature. This is true for exothermic reactions. So, the forward reaction is exothermic.

Dr. Abubacker
Reviewed by Dr. Abubacker

Physics Educator & NEET/JEE Specialist

Ph.D. in Physics with 19+ years of teaching experience.

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