Q. 50 mL of $H_{2}O$ is added to 50 mL of $1 \times 10^{- 3}$ M barium hydroxide solution. What is the pH of the resulting solution?

A) 3.0
B) 3.3
C) 11.0
D) 11.7
Explanation

(c)
In water, barium hydroxide is hydrolysed as followers
$Ba(OH)_{2} \rightleftharpoons {Ba}^{2 +} + \ 2{OH}^{-}$
Conc. Of ${Ba}^{2 +} = 1 \times 10^{- 3}M$
Conc. of $\left\lbrack {OH}^{-} \right\rbrack = 2 \times 1 \times 10^{- 3}M$
$= 2 \times 10^{- 3}M$
$pOH = \ - \log{\lbrack{OH}^{-}\rbrack}$
$\ \ \ \ \ \ \ \ \ = \ - \log{(2 \times 10^{- 3})}$
$\ \ \ \ \ \ \ \ \ = 2.69$
$pH + pOH = 14$
$\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ pH = 14 - pOH$
$= 14 - 2.69$
$\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ = 11.3$
$\approx 11.0$

Dr. Abubacker
Reviewed by Dr. Abubacker

Physics Educator & NEET/JEE Specialist

Ph.D. in Physics with 19+ years of teaching experience.

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