(d)
Formula of gypsum $= CaSO_{4}.\ 2H_{2}O$
Formula of plaster of Paris $= CaSO_{4}\ .\frac{1}{2}H_{2}O$
Difference of water molecule$= 2H_{2}O\ –\frac{1}{2}H_{2}O$
$\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ = 1\frac{1}{2}H_{2}O$