(b)
$LiNO_{3}$ behaves differently from other alkali metal nitrates.
$2LiNO_{3}\overset{\ \ \ \ \ \mathrm{\Delta}\ \ \ \ \ }{\rightarrow}\ Li_{2}O + 2NO_{2} + \frac{1}{2}O_{2}$
$NaNO_{3}\overset{\ \ \ \ \ \mathrm{\Delta}\ \ \ \ \ }{\rightarrow}\ NaNO_{2} + \frac{1}{2}O_{2}$