(a)
$\left( CaSO_{4} \right)_{2}\ .\ H_{2}O\$ is plaster of Paris. Since, on adding water, it sets into a hard mass due to the formation of gypsum, it is used for plastering the broken bones.
$\left( CaSO_{4} \right)_{2}\ .\ H_{2}O + 1\frac{1}{2}H_{2}O\ \longrightarrow 2CaSO_{4}\ .\ 2H_{2}O$
hard mass