(d)
Plaster of Paris is a whit powder. It changes into a hard mass called gypsum on mixing with water. There is a slight increase in volume during this process.
$CaSO_{4}\ .\frac{1}{2}H_{2}O + 1\frac{1}{2}H_{2}O\ \rightarrow CaSO_{4}\ .\ 2H_{2}O + Heat$
Plaster of Paris gypsum