(a)
Alum is a double salt having general formula $M_{2}SO_{4}M_{2}^{'}\left( SO_{4} \right)_{3}.24H_{2}O$ where $M$ is monovalent metal and $M^{'}$is trivalent metal. Potash alum has potassium (K) as monovalent metal. Potash alum is
$\ \ \ \ \ \ \ \ \ \ \ \ \ K_{2}SO_{4}.Al_{2}\left( SO_{4} \right)_{3}.24H_{2}O$.