(a)
[table] Column I | Column II ; Benzene | $(4n + 2)\pi$-electrons ; Ethylene | Mustard gas ; Acetaldehyde | Silver mirror ; Chloroform | Phosgene [/table]
Benzene has $6\pi$-electrons, $i.e.,$ it follows Huckel rule $(4n + 2)\pi$-electrons. Ethylene reacts with $S_{2}Cl_{2}$ to give mustard gas (war gas).