Q. The decreasing order of nucleophilicity among the nucleophiles (A) $CH_{3}C - O^{-}$ (B)$CH_{3}O^{-}$ $\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \parallel$ O (C)$CN^{-}$ (D)

A) (C),(B),(A),(D)
B) (B),(C),(A),(D)
C) (D),(C),(B),(A)
D) (A),(B),(C),(D)
Explanation

(b)
If acid is weak, its conjugate base (nucleophile) is strong and $vice\ versa.$
O O
$\ \ \ \ \ \ \ \ \ \ \ \ \ \parallel \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \parallel$
(A)$CH_{3} - C - O^{-}$ is conjugated base of $CH_{3}COH$ (I)
(B) $CH_{3}O^{-}$ is a conjugate base of $CH_{3}OH\ (II)$
(C) $CN^{-}$ is a conjugate base of HCN (III)
(D)$H_{3}$ [image:12_image303.emf] $SO_{3}^{-}$ is a conjugate base
Of [image:12_image304.emf]
Acidic nature of IV>I>III>II
and nucleophilicity of B>C>A>D.

Dr. Abubacker
Reviewed by Dr. Abubacker

Physics Educator & NEET/JEE Specialist

Ph.D. in Physics with 19+ years of teaching experience.