Q. Which of the following aromatic acid is most acidic?

A) [image:12_image44.emf]
B) [image:12_image45.emf]
C) [image:12_image46.emf]
D) [image:12_image47.emf]
Explanation

(b)
Due to resonance; the carbonyl group of benzoic acid is coplanar with the ring. If the electron withdrawing substituent (i.e., $- I\$showing) is present at $ortho$ position, it prevents the coplanarity and thus, the resonance. Hence, makes the acid more stronger.
Thus, among the given acids, $ortho$ hydroxy benzene acid is the most acidic.

Dr. Abubacker
Reviewed by Dr. Abubacker

Physics Educator & NEET/JEE Specialist

Ph.D. in Physics with 19+ years of teaching experience.