(a)
During thunderstorm, there is formation of $NO$ which changes to $NO_{2}$ and ultimately to $HNO_{3}$ (acid rain).
$N_{2} + O_{2} \rightarrow NO\overset{{\ \ \ O}_{2}\ \ \ }{\rightarrow}NO_{2}\overset{{\ \ \ O}_{3}\ \ }{\rightarrow}NO_{3} + O_{2}$
$NO_{3} + O_{2} \rightarrow N_{2}O_{5}\overset{H_{2}O\ \ \ }{\rightarrow}HNO_{3}(pH < 7)$