(d)
During the formation of photochemical smog the level of ozone in the atmosphere goes down.
$NO + O_{3}\overset{\ \ hv\ \ \ \ }{\rightarrow}\ NO_{2} + O_{2}$
In the atmosphere the organic compounds rapidly react with $O_{3},NO_{2}$ to form other noxious photochemical products known as peroxyacyl nitrates (PANs) and acrolein.
Photochemical smog occurs in warm, dry and sunny climate, generally during the day time while classical smog occurs in cool humid climate, generally in the early morning hours of winter months.