(a)
Given, angle of diffraction $(2\theta) = 90{^\circ}$
$\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \theta = 45{^\circ}$
Distance between two planes, $d = 2.28\ \mathring{\mathrm{A}}\$
$\ \ \ \ n = 2$ $\lbrack\because\$ Second order diffraction]
Bragg’s equation is
$\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ n\lambda = 2d\sin\theta$
$\ \ \ \ \ \ \ \ \ \ \ \ \ 2 \times \lambda = 2 \times 2.28 \times \sin{45{^\circ}}$
$\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \lambda = 1.612$