(d)
In fcc atoms are present at faces and corners.
Number of atoms in fcc = atoms at corners
+ atoms at faces of unit cell.
= (no. of corners $\times$ contribution by one atom)
+ (no. of faces $\times$ contribution by one atom)
$= \left( 8 \times \frac{1}{8} \right) + \left( 6 \times \frac{1}{2} \right) = 1 + 3 = 4$