(a) $\pi$ =CRT Hence, C =0.2 M R =0.082 L atm $mol^{- 1}K^{- 1}$ T =27+273 = 300 K $\ \ \ \ \ \ \$ $\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \pi$ =0.2$\times 0.082 \times 300\ K$ =4.92 atm.
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