Q. If sodium sulphate is considered to be completely dissociated into cations and anions in aqueous solution, the change in freezing point of water ($\mathrm{\Delta}T_{f}$), when 0.01 mole of sodium sulphate is dissolved in 1 kg of water, is ($k_{f} = 1.86\ Kkg\ mol^{- 1})\ \$

A) 0.0372 K
B) 0.0558 K
C) 0.0744 L
D) 0.0186 K
Explanation

(b)
$Na_{2}SO_{4} \rightarrow 2Na^{+} + SO_{4}^{2 -}$
van’t Hoff factor for$\ Na_{2}SO_{4}$ =3
$\mathrm{\Delta}T_{f} = i \times k_{f} \times m$
=3$\times 1.86 \times 0.01$
$\left\lbrack \because\ \ \ m = \frac{0.01}{1} = 0.01 \right\rbrack$
=0.0558 K

Dr. Abubacker
Reviewed by Dr. Abubacker

Physics Educator & NEET/JEE Specialist

Ph.D. in Physics with 19+ years of teaching experience.

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