(b)
Osmotic pressure ($\pi$)=CRT
Here, C = concentration of solution
C=$\frac{n}{V}$
n=$\frac{w}{m} = \frac{weight\ in\ gram\ of\ substance\ }{mol.weight\ ofsubstance\ }$
V=1L
C=$\frac{68.4}{342}$
$\pi$ =$\frac{68.4}{342} \times 0.082 \times 273$
=4.48 atm