(b)
Boiling point $\left( T_{b} \right) = 100 + \mathrm{\Delta}T_{b} = 100 + k_{b}m$
Freezing point $\left( T_{f} \right) = 0 - \mathrm{\Delta}T_{f} = - k_{f}m$$T_{b} - T_{f} = \left( 100 + k_{b}m \right) - ( - k_{f}m)$
$105 = 100 + 0.51m + 1.86m$
$2.37\ m = 5\ or\ \ m = \frac{5}{2.37} = 2.11$
$\therefore$ Weight of sucrose to be dissolved in 100 g water
$= \frac{2.11 \times 342}{1000} \times 100 = 72g$