(d)
$HX \rightleftharpoons {\ \ \ H}^{+} + X^{-}$
1 mole 0 0 initial
$1 - 0.3\ \ 0.3\ \ 0.3$ after dissociation
Total moles $= 0.7 + 0.3 + 0.3 = 1.3$
$\therefore\ \ i = \frac{1.3}{1} = 1.3$
$\mathrm{\Delta}T_{f} = i \times k_{f} \times m = 1.3 \times 1.85 \times 0.2 = 0.481℃$
$\therefore T_{f} = T - \mathrm{\Delta}T_{f} = 0 - 0.481℃ = - 0.481℃$