(d)
Van’t Hoff factor (i) is given by
$i = \frac{observed\ value\ of\ colligative\ property}{normal\ value\ of\ colligative\ property\ }$
The normal value of colligative property is the theoretically calculated value assuming no association or dissociation.
$\therefore\ \ \ \ \ \ \ \ \ \ \ \ i = \frac{\pi_{obs}}{\pi_{cal}}$