(c)
We know that,
w(mass of solute) = $\frac{m \times \mathrm{\Delta}T_{f} \times W}{1000 \times k_{f}}$
m= mol. wt. of urea (60)
$\mathrm{\Delta}T_{f} = 0.186℃$
$k_{f}$ =1.86${^\circ}$, W =500 g
= $\frac{60 \times 0.186 \times 500}{1000 \times 1.86}$
=3g