Q. Vapour pressure of$\ CCl_{4}\$at $25℃$ is 143 mm of Hg and 0.5 g of a non-volatile solute (mol. wt=65) is dissolved in$100$ $mL\ CCl_{4}$. Find the vapour pressure of the solution. (Density of $CCl_{4} = 1.58\ g/cm^{2}$)

A) 94.39 mm
B) 141.93 mm
C) 134.44 mm
D) 199.34 mm
Explanation

(b)
$\frac{p^{0} - p_{s}}{p^{0}} = \frac{w \times M}{m \times W}$
$\frac{143 - p_{s}}{143} = \frac{0.5}{65} \times \frac{154}{1.58 \times 100}$
[$\because$ molecular weight of $CCl_{4} = 154$ and weight=density$\times$volume]
$143 - p_{s} = 1.07\ \Rightarrow p_{s} = 141.93\ mm$

Dr. Abubacker
Reviewed by Dr. Abubacker

Physics Educator & NEET/JEE Specialist

Ph.D. in Physics with 19+ years of teaching experience.

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