(b)
$\frac{p^{0} - p_{s}}{p^{0}} = \frac{w \times M}{m \times W}$
$\frac{143 - p_{s}}{143} = \frac{0.5}{65} \times \frac{154}{1.58 \times 100}$
[$\because$ molecular weight of $CCl_{4} = 154$ and weight=density$\times$volume]
$143 - p_{s} = 1.07\ \Rightarrow p_{s} = 141.93\ mm$