Q. $AgNO_{3}\ (aq)$ was added to an aqueous KCl solution gradually and the conductivity of the solution was measured. The plot of conductance $(\Lambda)$ $versus$ the volume of $AgNO_{3}$ is

A) (P)
B) (Q)
C) (R)
D) (S)
Explanation

(d)
As $AgnO_{3}$ is added to solution , KCl will be displaced according to following reaction $AgNO_{3}\ (aq) + \ KCl\ (aq) \longrightarrow AgCl_{(s)} + \ KNO_{3}\ (aq)$
For every mole of KCl displaced from solution, one mole of $KNO_{3}$ comes in solution resulting in almost constant conductivity. As the end point is reached, added $AgNO_{3}$ remain in solution increasing ionic concentration, hence conductivity increases.

Dr. Abubacker
Reviewed by Dr. Abubacker

Physics Educator & NEET/JEE Specialist

Ph.D. in Physics with 19+ years of teaching experience.