(a)
$A\overset{\ \ \ \ k_{1}\ \ \ \ }{\rightarrow}B\overset{\ \ \ \ k_{2}\ \ \ \ }{\rightarrow}C\overset{\ \ \ \ k_{3}\ \ \ \ }{\rightarrow}D$
$\because k_{3} > k_{2} > k_{1}$
As $k_{1}$ is slowest hence $A \rightarrow B$ is the rate determining step of the reaction