Q. The rate constant of a reaction at temperature 200 K is 10 times less than the rate constant at 400 K. What is the activation energy $\left( E_{a} \right)$ of the reaction?

A) $1842.4\ R$
B) $921.2\ R$
C) $460.6\ R$
D) $230.3\ R$
Explanation

(b)
At $T_{1} = 200\ K,\ T_{2} = 400\ K,\ k_{1} = k,\ \ k_{2} = 10\ k$
$\because\log\frac{k_{2}}{k_{1}} = \frac{E_{a}}{2.303R}\ \left( \frac{T_{2} - T_{1}}{T_{1}\ \bullet T_{2}} \right)$
$\log\frac{10\ k}{k} = \frac{E_{a}}{2.303R}\ \left( \frac{400 - 200}{400 \times 200} \right)$
$E_{a} = 921.2\ R$

Dr. Abubacker
Reviewed by Dr. Abubacker

Physics Educator & NEET/JEE Specialist

Ph.D. in Physics with 19+ years of teaching experience.