(d)
Gold number is the amount of substance in milligram that is required to prevent coagulation of $10\ {cm}^{3}$ of gold sol by addition of $1\ mL\ of\ 10\%\ NaCl$ solution.
Convert 0.025 g into milligram = 25
$0.025\ g\ starch = 0.025 \times 1000 = 25\ mg$
Thus, the gold number of starch = 25