(d)
Concentrated $H_{2}SO_{4}$ has dehydrating property. When cellulose comes in contact with conc $H_{2}SO_{4}$, it removes water from cotton leaving only black carbon in the form of charred particles
$\left( C_{6}H_{12}O_{6} \right)_{x} \rightarrow 6C + 6H_{2}O$
Charred particles